Hi Folks, Gone n Finaly Done it....Took out my dreaded PCI USB2.0 n threw it in the corner...Benchmark for the HD on it was 1 (YES 1)
Not got a clue what was wrong n got fed up of getting frustrated with the long wait of things to Open n Install on it....Any way
This is what i have now done......

Lite-On DVD-Rom 166S is Master on the IDE0 (on its own)
NEC 2500A is Master on the IDE1 (Secondary Master) & the
Lite-On CDR/RW Writer is Slave on IDE1
Not yet Tried em out!!

Maxtor 40Gbt with OS on it C: n E: is Master on the First 80pin cable on PCI ATA100, Maxtor 80Gbt is Slave on same cable...Benchmark=C:39Write n 36read......E:37Write n 31read
D:54write n 16read

Maxtor 120Gbt is set to Master on the Other Ribbon Cable but is showing up as "SLAVE"<<<<Any Ideas as to why its showing as SLAVE...Should it not be MASTER!! or Don't it matter..(to me it does) K: 41write n 47read quite fast really...1.2Ghz Athlon....
Thanks All....Ya doing a Great Job as usual....
It is Working Perfectly, as is the Other Hard Drives